Organic Chemistry 354 Quiz - December 13, 1999

Dr. Sundin

1. Locate the isoprene units in the following terpenes.
Answer

2. Eleostearic acid, C18H30O2, is found in tung oil. Upon mild hydrogenation, eleostearic acid is converted to stearic acid, C18H36O2. Upon very mild hydrogenation, eleostearic acid is converted to a mixture of acids, one of which is oleic acid, C8H17CH=CHC8H15O2. Treatment of eleostearic acid with hot, acidic potassium permanganate yields 1 part pentanoic acid, C5H10O2, 1 part nonanedioic acid, C9H16O4, and 2 parts of oxalic acid, HO2C-CO2H. What is the structure of eleostearic acid? Answer

3. Many organic compounds found in living systems are complex molecules which can be characterized, in part, by simply listing the products of the complete hydrolysis of the complex molecule. "Characterize" the following groups of naturally occurring molecules by giving the class name(s) (or general structure if you have forgotten the name) of the products of complete hydrolysis. Also, give the name of the functional groups which bond together the components of these complex molecules.

a. DNA

b. RNA Answer

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