Organic Chemistry 354 Quiz - December 9, 1999

Dr. Sundin

1. Many organic compounds found in living systems are complex molecules which can be characterized, in part, by simply listing the products of the complete hydrolysis of the complex molecule. "Characterize" the following groups of naturally occurring molecules by giving the class name(s) (or general structure if you have forgotten the name) of the products of complete hydrolysis. In the event that two (or more) of the following are so characterized identically (same names of hydrolysis products), expand on your answer sufficiently so that one can clearly understand the distinct difference(s) between these complex molecules. Also, give the name of the functional group which bonds together the components of these complex molecules.

a. wax
b. fat
c. oil (as in vegetable oil, not petroleum) Answer

2. Draw structures of three different forces (attractions) responsible for maintaining the conformation of an enzyme. Answer

3. Enzymes catalyze reactions in living organisms. Various portions of the enzyme (either a single amino acid or groups of amino acids) play critical roles (functions) in this catalytic process. For enzymes in general, list three different roles (roles are defined broadly) that portions of the enzyme might do as the enzyme performs its overall function. Answer

4. a. Which has a higher saponification number, glyceryl tristearate or glyceryl trilinoleate? (Linoleic acid is a straight chain acid with formula C18H32O2.) Answer

b. Which has a higher iodine number, glyceryl tristearate or glyceryl trilinoleate? Answer

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