Organic Chemistry 354 Quiz - October 14, 1999

Dr. Sundin

1. Encircle the activating groups and underline the meta directors for electrophilic aromatic substitution:

Answer

2. Draw the following using the dashed line, wedge technique (primary emphasis is on stereochemistry):

a. (R)-2-bromobutane. Answer

b. The enantiomer of what you drew in part 2. a. (It should be drawn in such a way that one can readily see that it is an enantiomer!) Answer

c. A constitutional isomer of what you drew in part 2. a. Answer

3. Determine if the following structures are chiral and if so, determine if they are R or S.

Answer

Answer

Answer

Answer

Answer

Answer

4. Compound G, C4H7Cl, is optically active. G did not react with basic permanganate solution. Give a three dimensional structure of one of the four isomers which could be G. Regular Answer Chime Answer

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