ORGANIC CHEMISTRY 354

ACIDITY OF ALPHA HYDROGENS

REACTIVITY OF ENOLATES

ALKYLATION OF ENOLATES

ACIDITY OF ALPHA PROTONS - ENOLATES

RELATIVE ACIDITIES

ENOLATES

  • BETTER THAN ENOLS FOR SYNTHESIS
  • RELATIVELY STABLE SOLUTIONS OF PURE ENOLATES CAN BE PREPARED
  • MUCH MORE REACTIVE THAN ENOLS.

ALKYLATIONS (GENERAL)

NATURE OF CARBONYLS AND BETA-DICARBONYLS

MALONIC ESTER SYNTHESIS

ACETOACETIC ESTER SYNTHESIS

OTHER BETA-KETO ESTER SYNTHESES

DIRECT ALKYLATION OF ESTERS, KETONES, AND NITRILES

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