ORGANIC CHEMISTRY 354

TENTATIVE SYLLABUS

DR. SUNDIN

UNIVERSITY OF WISCONSIN-PLATTEVILLE

FALL, 1997

The readings and problems are from Fundamentals of Organic Chemistry, 3rd Ed., by John McMurry.

DATE: READING ASSIGNMENT; PROBLEMS

September 2 Introduction: pages xix-xx, 1-2. Notes
September 4 Bonding: pages 2-11; page 29: # 25, 26, 27, 28, 29, 30, 37, 45.
September 5 Hybridization, Molecular Shapes: pages 11-19; page 29: # 31, 32, 33, 34, 35, 36, 38, 46, 52, 53, 56.
September 8 Polarity, Electronegativity, Acidity: pages 19-26; page 30: #39, 40, 41, 42, 43, 47, 48, 49, 50, 51.
September 9 Functional Groups, Alkane Isomers: pages 32-39; page 65: # 24, 25, 26, 27, 28, 30, 32
September 11 Alkyl Groups, Alkane Nomenclature: pages 40-46; page 66: # 31, 33, 34, 35, 36, 37, 42, 48.
September 12 Alkane Properties, Conformations: pages 46-52; pge 67: #38, 39, 47.
September 15 Cycloalkanes: pages 52-62; page 67: # 40, 41, 49, 50, 51, 52, 53, 54, 55.
September 16 Alkenes; Structure, Nomenclature: pages 70-80; page 97: # 22, 24, 27, 28, 29, 30, 32, 33, 34, 35, 37, 38, 39, 41, 45.
September 18 Exam I, pages 1-69
September 19 Infrared Spectroscopy: pages 378-386; page 405: # 18, 19, 23, 30, 31, 34, 35.
September 22 Types of Organic Reactions, Mechanisms: pages 80-87; page 97: # 25, 26, 43, 46, 47.
September 23 Rates, Equilibrium, Energy: pages 87-94; page 99: # 48, 49, 50, 51, 52, 53, 54, 55, 56.
September 25 Markovnikov's Rule: pages 101-106
September 26 Addition Reactions: pages 107-117
September 29 Elimination Reactions, Alkynes: pages 117-120, 127-132
September 30 Conjugation, Allylic Cations, Resonance: pages 120-127
October 2 Aromaticity, Aromatic Nomenclature: pages 141-147
October 3 Electrophilic Aromatic Substitution: pages 147-154
October 6 Reactivity, Directive Effects, Synthesis: pages 154-163
October 7 Chirality: pages 171-181
October 9 EXAM II: pages 70-170, 378-386
October 10 Configuration, Sequence Rules: pages 181-186
October 13 Meso Compounds, Diastereomers, Racemic Mixtures: pages 186-192
October 14 Alkyl Halides: Nomenclature, Preparation, Reactions: pages 199-206
October 16 Nucleophilic Substitution: pages 206-217
October 17 Eliminations: pages 217-224
October 20 Alcohols, Phenols, Ethers: Nomenclature, Hydrogen Bonding, Acidity: pages 232-239
October 21 Synthesis, Reactions: pages
October 23 Synthesis, Reactions: pages 245-252
October 24 Aldehydes & Ketones: Nomenclature, Properties: pages 260-265
October 27 Synthesis, Reactions: pages 265-267
October 28 Nucleophilic Additions: pages 268-279
October 30 EXAM III: pages 171-267
October 31 Carboxylic Acids, Derivatives: Nomenclature, Acidity: pages 285-292
November 3 Carboxylic Acids: Synthesis, Reactions: pages 292-300
November 4 Anhydrides, Esters: pages 300-309
November 6 Amides, Nitriles, Polymers: pages 309-316
November 7 Nuclear Magnetic Resonance Spectroscopy: pages 389-403
November 10 Tautomers, Carbonyl Alpha Substitutions: pages 325-331
November 11 Alpha Hydrogen Acidity, Enolates: pages 331-337
November 13 Condensations, Ultraviolet Spectroscopy: pages 338-345, 386-389
November 14 Amine Nomenclature, Basicity: pages 350-359
November 17 Amine Synthesis, Reactions: pages 359-366
November 18 Heterocycles, Alkaloids, Dyes: pages 366-372
November 20 EXAM IV: pages 268-366, 386-409
November 21 Carbohydrates, Classification, Glucose: pages 410-418
November 24 Monosaccharides: pages 419-429
November 25 Disaccharides, Polysaccharides: pages 429-436
December 1 Amino Acids: pages 442-450
December 2 Peptides: pages 450-460
December 4 Proteins: pages 460-465
December 5 Enzymes: pages 465-467
December 8 Lipids: pages 473-483
December 9 Nucleic Acids: pages 483-502
December 11 Metabolism" pages 507-524
December 12 EXAM V: pages 366-529
December 17 FINAL EXAM :10:00-11:50 am: ACS Standardized