Organic Chemistry 354 Quiz - December 12, 2000

Dr. Sundin

1. Consider this molecule:

a. Is this molecule a monosaccharide, a disaccharide, a trisaccharide, or a polysaccharide? Answer

b. Is this molecule a reducing sugar? Answer

c. Is the "hexose" portion of this molecule an aldose or ketose? Answer

d. Is the "pentose" portion of this molecule an aldose or ketose? Answer

e. Is either the "pentose" or the "hexose" portion of this molecule a deoxy sugar? Answer

2. Optically active aldopentose A was oxidized with nitric acid to give optically active B. Degradation of A gave optically active aldotetrose C. Degradation of C gave D-glyceraldehyde. Nitric acid oxidation of C gave optically inactive D. Give Fischer projections of A, B, C, D, and D-glyceraldehyde. Answer

3. There is another aldopentose which when oxidized with nitric acid also gives diacid B. Encircle the structure of this aldopentose below.

Answer

4. Without drawing any structures, compare and contrast the structures of cellulose and soluble starch. Answer

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