Organic Chemistry 354 Quiz - September 28, 2000

Dr. Sundin

1. Redraw the following compounds in a vertical array with the least stable on top and the most stable on the bottom: Answer

2. State Markovnikov's Rule. Answer

3. Answer the following for the two step process:

A ---> B, Ea = 11, DH = +3

B ---> C, Ea = 4, D = -7

_________a. Ea for reaction A ---> C

_________b. Ea for reaction C ---> A

_________c. DH for reaction A ---> C

_________d. DH for reaction C ---> A

Answer

4. Redraw the following ions in a vertical array with the least stable on top and the most stable on the bottom: Answer

5. Give the structure of the product and mechanism of the following two step reaction using the curved arrow notation:

CH2=C(CH3)2 + HCl--> C4H9Cl Answer

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